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The!Mad!Lab!

IB Chemistry G12

February 21-25, 2016

2/23/2016

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Housekeeping: We have to get cracking if you are taking the Ch 4 Exam on March 8.  Start working through the practice questions, as I am determined to get through Section 4.3 this week.  So I'm going to roll out your homework questions for the week:

p. 132 #14-17, p. 136 #18-20, p. 138 #21, p. 143 #23

These problems are going into the gradebook as an assignment and I'll be looking for completion on Wednesday & Thursday.

Agenda:
1.  VSEPR Theory & Molecular Geometry.

Lesson Objectives.  By the end of this lesson, you should be able to:

1.  Explain VSEPR Theory.
2.  Draw Lewis structures of covalent compounds using VSEPR Theory.
3.  Use VSEPR Theory to predict molecular geometry of different compounds
4.  Use VSEPR Theory to predict molecular polarity.
5.  Draw and describe resonance structures of different compounds, such as benzene, carbonate, and ozone.
6.  Explain the properties of giant covalent compounds in terms of their structures,

Content Review: 
Links:  VSEPR Theory   Molecular Geometry  
Textbook Readings: Chapter 4.

Student Missions:
Mission 1: What Molecules Look Like.  VSEPR stands for Valence Shell Electron Pair Repulsion.  This theory helps us to predict the shape of molecules using their valence electrons.  There are six steps to drawing Lewis structures using the VSEPR theory. Page 130 lists the six rules.  Mr. Anderson walks you through the process.  We will work some practice problems in class.
Let's Practice!!

Mission 2:  Keeping Things Straight.  Remember that the book (and therefore the exams) will refer to shared pairs of electrons as electron domains.  Here is what we know so far:

Molecules (or species) with two electron domains tend to be linear with bond angles of 180 degrees.

Species with three electron domains tend to be trigonal planar with bond angles of 120 degrees.  But if one of the electron domains is a lone pair (or unshared pair [two dots]), it doesn't show in the overall shaped.  This results in species that are bent and have bond angles of 117 degrees.

Species with four electron domains tend to be tetrahedral and have bond angles of 109.5 degrees.

Pages 136-7 provide excellent summary tables of these shapes.

Mission 3:  Resonance.  Delocalization is when bonding electrons are not restricted to specific positions in molecules.  They can spread out and give greater stability to thee molecule or ion.  This happens frequently in molecules when there is more than one possible position for a double bond within a molecule.  Example: Ozone
As a result, molecules like these demonstrate resonance.  The Lewis structures are called resonance structures, as there are multiple versions of where the delocalized electrons can be.  See the carbonate example on page 140.  Also look at the benzene example on page 141.  This is a specific example you are expected to know.

Resonance gives special properties to the structures where it occurs.  It affects bond lengths and strengths, which influence reactivity.  Acid and base strengths can be explained by resonance.

Play with this simulation.

Mission 4: 

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Supplemental: Formula of a Hydrate

2/16/2016

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Today you guys are doing the formula of a hydrate lab.  You are going to burn off the water of a hydrated salt and calculate the empirical formula.  You'll need to go back to Chapter 1 and review empirical and molecular formulas.  This is our second chance to do an EF/MF lab.

Below is a video walking you through how to do the lab.  It is suggested that you watch it before you begin working on the lab.
Below are some links to lab reports that you should review.  They will help you understand what kind of information and data should be in your lab report.  While you may use them as a resource, you better not plagiarize them.

1. http://theoakwoodschool.org/blog/kthompson/files/2011/08/Lab-Report-Sample.pdf
2.http://swc2.hccs.edu/pahlavan/intro_labs/Exp_18_Percentage_and_Formula_of_a_Hydrate.pdf
3.  Teachnlearnchem.  This is a .doc so it is linked.

​Rough draft is due February 24.  Final draft is due March 3.

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February 7 - 11, 2016

2/8/2016

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Housekeeping: As of now, you have a "0" for the periodic timeline assignment.  It was due Thursday, regardless of the fact that we didn't have class.  Your decision, so live with it.

We are now in Chapter 04: Bonding.

Agenda:
1. Discussion of ion formation.
2. How ionic/covalent bonds are formed.
3. How ionic/covalent compounds are named.
4. Writing ionic formulas.

Lesson Objectives.  By the end of this lesson, you should be able to:
1.  Determine which elements form cations and which elements form anions.
2.  Contemplate the structure of an ionic bond based on valence electrons.
3.  Determine when covalent bonds are formed and which elements form them.
4.  Predict the name of an ionic compound and a covalent compound.
5.  Explain the difference between polar and nonpolar molecules.


Content Review: 
Links:  Chemical Bonding  This page contains PowerPoints that cover ionic and covalent bonding and a summary table.  This is a PowerPoint on Chemical Names & Formulas
Textbook Readings: Chapter 4.

Student Missions:
Mission 1:  Ions, Ions, Ions!  Recall that the group number on the periodic table represents the number of valence electrons in that group.  Also recall that group 18, the noble gases, have stable octets.  The objective for any element that is not a noble gas is to lose or gain electrons to have a noble gas configuration.  Stability is key.

Elements in G1 will LOSE their valence electrons to form ions with a +1 charge. Elements in G2 will LOSE theirs to form ions with a +2 charge.  Elements in G13 will lose theirs to form ions with a +3 charge.  Any time an element LOSES a valence electron, a cation is formed.  Cations are positively charged ions.  Metallic elements form cations.

Conversely, elements in G15 will GAIN 3 electrons to form ions with a -3 charge. Elements in G16 will GAIN 2 electrons to form ions with a -2 charge, and elements in G17 will GAIN 1 electron to form an ion with a -1 charge.  Any time an element GAINS a valence electron, an anion is formed.  Anions are negatively charged ions.  Nonmetals form anions.
Picture
Transition metals have electron configurations that allow them to lose different numbers of electrons from their d subshell and form ions with different oxidation states.  An oxidation state is the charge on an ion.  The ions have different properties, such as forming compounds with different colors.  An example would be the copper I and copper II ions ( Cu+ and Cu+2).  One is green, the other blue.

Polyatomic ions are ions that are made up of several atoms covalently bonded, but have a positive or negative charge.  I have given you a ion reference chart to use in class, but you need to memorize the different polyatomic ions, as they are not in the data booklet and you cannot use the ion chart on the test.
Picture
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The images above (courtesy of wikipedia.org and http://sphweb.bumc.bu.edu) show the crystal lattice structure of salt (NaCl).  The electrostatic attraction between cations and anions causes the ions to surround themselves with the opposite charged ion.  The coordinate number is the number of surrounding ions.  For salt, the coordination number is 6, as each Na+ is surrounded by 6 Cl-.  Because these structures can get big, their formulas are merely the ratios of ions present.  The simplest ratio is called a formula unit (fmu).

Lattice energy is a measure of the strength of attraction between ions within the lattice.  The energy is greater for small, highly charged ions.  Because of their lattice structures, ionic compounds have high melting and boiling points.  The electrostatic attraction  between the ions are strong and requires a lot of energy to break.  Therefore, they are solids at room temperature and melt at very high temperatures..  When the charge is greater, the MPs and BPs are higher.

Volatility is the tendency of a substance to vaporize.  Ionic compounds have a low volatility, or is non-existent.  This means that they do not tend to vaporize because the bonds are too strong.
Solubility is the tendency of a substance to dissolve.  Partial charges in water (a polar molecule) are attracted to opposite charges in an ionic compound and can dislodge the ions.  When ions are surrounded by water, they become hydrated.  Then the compound can dissolve.  The state symbol for a compound dissolved in water is (aq) for aqueous.  Nonpolar solvents do not have a charge, and therefore the ions do not pull apart.  As a result, the substance is insoluble.

Conductivity & Brittleness.  Based on an ability of a compound to conduct electricity, the ions have to be able to move.  Therefore they cannot conduct electricity in the solid (s) state.  The compound has to be molten (or liquid (l)) or dissolved in water (aq) to conduct electricity.

​The ionic crystal lattice can shatter when a force is applied, so therefore it is brittle.

Homework:  Practice handout on formula writing.  Page 118, #1-6 and p. 122 #7-9.

Mission 2: Sharing is Caring.  Covalent bonds are the result of valence electrons being shared in order to achieve stable octets.  If you think back...way back...to the short lesson on Lewis Dot, you'll recall that certain elements contained a certain number of dots that represented their valence electrons.
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Anyhoo, if you take a look at groups 15, 16 & 17 (the nonmetals), this is where covalent bonding takes place.  These elements can bond with themselves to share a pair (or two, or three) of electrons to form stable octets.  Take a look below.  Fluorine will share a pair of electrons with another fluorine and a single covalent bond is formed (represented by a line).
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Group 16 elements will share two pairs of electrons (double covalent bond) and group 15 elements will share three pairs of electrons (triple covalent bond).  Again, the goal is stability.  The Octet Rule rules all.

Here is an interactive on covalent bonding.  Play with it.

There are seven elements that are found in nature covalently bonded to each other. They are called diatomic elements.  A useful memory aid is HONI Bring Fried Clams.  So when you're writing these elements in chemical equations, you need to make sure you write them correctly.


Coordinate covalent bonds are bonds where one atom contributes both bonding electrons.  You demonstrate them in structural formulas using an arrow that shows where the electrons came from.  Once formed, the coordinate covalent bond is just like any other bond.  Carbon monoxide is a good example of this.
Picture
Bond Disassociation Energy.  This is the energy required to break covalent bonds.  The unit is usually given in kJ/mol, which is the energy required to break one mole of bonds. There is a table on page 236 in your textbook, or you can look below.  Simply put, the larger the BDE, the stronger the covalent bond.  Single bonds are easier to break than double bonds, and double bonds are easier to break than triple bonds, and so on and so forth.  This will become important when we get to thermochemistry.

Image courtesy of butane.chem.uiuc.edu.
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Mission 3: Electron Tug-of-War.  Because covalent bonding involves sharing of electrons, there can be differences in how the electrons are shared between the bonded atoms. The character (or behavior) of the molecules depends on the kind of and number of atoms joined together, which in turn, determine molecular properties.

There are pictures on pages 125-6 that demonstrates how the electrons are shared between atoms.  If you think of it in terms of tug-of-war, there will either be an even pull on the electrons, or an uneven pull on the electrons.  An even pull means that the molecule does not orient in any particular direction, which makes it symmetric and considered to be nonpolar.  If there is an uneven pull on the electrons, then the molecule will orient in a particular direction (because the unshared pairs of electrons take up more space than shared pairs) and become asymmetric.  These molecules are considered to be polar.
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Examine the molecules above.  Atoms that have multiple lone pairs will take up more space than atoms with shared pairs.  This warps the orientation of the molecule and thus, makes it polar.  But if every atom is the same or has the same number of lone pairs, then the molecule does not warp and is nonpolar.

​Take a look at this flash.


Another way to determine polarity is using electronegativity values.  As the electronegativity difference between two atoms increase, the polarity of the bond increases.  If the difference is greater than 2, the electrons will likely be transferred from one of the atoms.  When this happens, an ionic bond forms.  

Homework:  Watch the videos and review the material from Mission 2.  Complete the problems on page 128.

Mission 4:  The Name Game.  Go to "Content Review" and review the naming powerpoint to learn the rules of naming both ionic and covalent compounds.  We will go through this in detail next class.

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